Research Archive

Here, we describe a single molecular assembly electrode that duplicates the key components of PSII.

The order in which a ring-closing metathesis and enolate oxidation were performed on this compound dictated the relative stereochemistry of the target.

This review summarizes the advancements in the field over the last decade, encompassing all aspects of the DSC technology: theoretical studies, characterization techniques, materials, applications as solar cells and as drivers for the synthesis of solar fuels, and commercialization efforts from various companies.

Herein, we synergistically combine RAFT and step-growth polymerization mechanisms, by employing a highly selective insertion process of a single monomer with a RAFT agent, to achieve RAFT step-growth polymerization.

This article describes stereodivergent Cu-catalyzed borylative cyclizations of racemic β-oxo acid derivatives bearing tethered pro-nucleophilic olefins to deliver highly functionalized cyclopentanols containing four contiguous stereogenic centers.

Here, we show that brush elastomers made by ring-opening metathesis polymerization (ROMP) of norbornene-terminated poly(dimethylsiloxane) macromonomers are less extensible than brush elastomers with the methacrylate backbone yet not as extensible (λmax) as predicted by the strain-stiffening parameter (β) derived from fitting the experimental stress–strain curves.

This study uses dynamic mechanical analysis (DMA) to probe thermal relaxations of a systematic set of polymers based around the benzodithiophene (BDT) moiety.

Efficient excited-state electron transfer between an iron(III) photosensitizer and organic electron donors was realized with green light irradiation.

Now, poly(acrylic acid) from diaper waste has been converted into valuable pressure-sensitive adhesives through an open-loop recycling method that is cost-effective and environmentally competitive.

We used an in vivo assay for TOR activity together with global proteomic and phosphoproteomic analyses to assess differences between wild-type and vip1-1 in the presence and absence of rapamycin.