Research Archive

We report the synthesis of eleven 2,2′-bipyridine (bpy) ligands functionalized for covalent immobilization on either metal oxide or hydrogen-terminated silicon surfaces.

Herein, we report the preferential oxidative addition of a phosphinite P−O bond at Ni over an N−H bond and interrogate both the mechanism of this bond activation and the microscopic reverse reaction by reconstructing the P−O bond using phosphorus electrophiles.

In the rhenium hexakis(arylisocyanide) complexes, [Re(CNAr)6]n+ (CNAr = 2,6-dimethylphenylisocyanide), the isocyanide ligands facilitate ligand-to-metal charge transfer transitions in the rhenium(II) species and metal-to-ligand charge transfer transition in the rhenium(I) species.

Herein, we communicate a strategy for the divergent functionalization of alkynes with photoexcited acridinium organic dyes, presumably via the formation of vinyl cation radicals as key intermediates.

A series of injectable polysaccharide hydrogels are prepared with oxidized dextran and diethylenetriamine-modified carboxymethylcellulose (CMC) or hyaluronic acid (HA).

The current work introduces a new method utilizing PILSNER for the examination of the particles generated during ESI using simple analysis techniques with a commercially available potentiostat.

To this end we introduce analysis of liquid particles in aerosols via charge-induction amperometry (ALPACA), an extremely simple potentiostat-based technique capable of on-line, rapid measurement of the aggregate charge of aerosol particles.

A practical method for the efficient and enantioselective preparation of versatile ketones and aldehydes that contain an α-quaternary stereocenter is described.

Here, we identified and characterized the amide N-methyltransferase DtpM that is encoded >400 kb outside of the thiolutin gene cluster.

The crosslink density was tuned by loading the functionalized networks with a controlled fraction of dormant crosslinkers and crosslinker scavengers, such as furan-capped bis-maleimide and anthracene, respectively.

Here we show that dynamic combinatorial libraries (DCLs) with simple building blocks can be templated with a fluorophore and subsequently used as sensors to form an array that differentially detects each PFAS species and various mixtures thereof.

We identify two separate and distinct double-stranded, RNA motifs (dsRNA stickers) that promote N-protein condensation.