Here, we show that dried CAHS D gels (i.e., aerogels) retain the structural units of their hydrogels, but the details depend on prelyophilization CAHS concentrations.
We review the use of nuclear magnetic resonance (NMR) spectroscopy to assess the exchange of amide protons for deuterons (HDX) in efforts to understand how high concentration of cosolutes, especially macromolecules, affect the equilibrium thermodynamics of protein stability.
Here, we identified genes that are likely regulated by Pvf using the model strain P. entomophila L48 which does not contain other known quorum sensing systems.
Here we report that lattice distortion in iodide/bromide mixed perovskites is correlated with the suppression of phase segregation, generating an increased ion-migration energy barrier arising from the decreased average interatomic distance between the A-site cation and iodide.
Here, we explore the effects of sunlight and oxidants on aqueous solutions of glyoxal and S(IV), and on aqueous aerosol exposed to glyoxal and SO2.
Demonstrated is the successful A2 + B2 RAFT step-growth polymerization of bis-acrylamides using a bifunctional trithiocarbonate chain transfer agent as the comonomer.
Using broadband dielectric spectroscopy, we measured the Tg of organic mixtures containing isoprene epoxydiol (IEPOX)-derived SOA components, including 2-methyltetrols (2-MT), 2-methyltetrol-sulfate (2-MTS), and 3-methyltetrol-sulfate (3-MTS).
Here, the effect of relative humidity (RH) on the deposition velocity (vd) and reaction probability (γ) of a model ROOH to naturally soiled indoor glass surfaces was investigated; specifically, by using authentic isoprene hydroxy hydroperoxide (1,2-ISOPOOH) as the model compound.
We report the C–H xanthylation of poly(caprolactone), a biodegradable polyester, which results in changes in materials properties even at small incorporations.
Here we show that peptides containing tyrosine and cysteine are rapidly cyclized upon tyrosinase treatment.
Herein, we disclose a simple catalytic crystallization-driven enantio- and diastereoselective Mannich reaction for the synthesis of stereodefined α-monosubstituted-ß-keto esters, dissymmetric ß-diesters, dissymmetric ß-diketones, and ß-keto amides that productively leverages product epimerization in solution.
We investigate how the spin-orbit-coupling-induced lifting of the spin degeneracy depends indirectly on constituting organic motifs in two-dimensional hybrid organic-inorganic perovskites.