Abstract The ligand-to-metal charge transfer (LMCT) transitions of [Re(dmpe)3]2+ (dmpe = bis-1,2-(dimethylphosphino)ethane) were interrogated using UV/Vis absorbance spectroscopy, photoluminescence spectroscopy, and time-dependent density…
Dempsey, Jillian
Abstract Mesoporous anatase TiO2, mixed anatase/brookite TiO2, and rutile-type SnO2 nanocrystalline films were coated with ultrathin (<5 nm) TiOx by the atomic…
Abstract Defects arising on the surfaces of semiconductor quantum dots (QDs) limit the applications of these otherwise promising materials. Efforts…
Abstract Electrochemical methods are coupled with chemical oxidant-based analytical strategies to evaluate the oxidative reactivity of the platinum(II) diimine complex…
Abstract Two-electron, one-proton reactions of a family of [CoCp(dxpe)(NCCH3)]2+ complexes (Cp = cyclopentadienyl, dxpe = 1,2-bis(di(aryl/alkyl)phosphino)ethane) form the corresponding hydride…
Abstract Semiconductor nanocrystals exhibit attractive photophysical properties for use in a variety of applications. Advancing the efficiency of nanocrystal-based devices…
Abstract Photoelectrodes consisting of wide-band gap metal oxides functionalized with chromophores and catalysts are a potential low-cost solution to generate…
Abstract The mechanism for interfacial electron transfer (ET) from a metal oxide core|shell nanostructure to a [RuIII(2,2′-bipyridine)2(4,4′-(PO3H2)2-2,2′-bipyridine)]3+ sensitizer was probed through…
July 31, 2020 By University Communications Department of Energy funds milestone North Carolina-led initiative to advance solar energy research The…